Salma Hayek was no stranger to Hollywood but gained even more fame after meeting her husband, Francois-Henri Pinault.

Francois is the CEO of the company Kering which means the fashion mogul is easily worth more than $19 billion to date. The couple became official in 2006 with their pregnancy being announced quickly afterward; now both stars are parents to daughter Valentina. A few years later in 2009, the pair wed in Paris, but things were on the rocks after Francois was accused of fathering another child, a claim he strongly denied.